Bis(2,2′-bipyridine)(pyridin-2-olato)ruthenium(II) hexafluoridophosphate benzene hemisolvate
نویسندگان
چکیده
In the title compound, [Ru(C(5)H(4)NO)(C(10)H(8)N(2))(2)]PF(6)·0.5C(6)H(6), the Ru(2+) cation has a distorted octa-hedral RuN(5)O coordination environment. This complex is more distorted than the closely related ruthenium complex containing a pyridine-2-thiol-ate ligand [Santra et al. (1997 ▶). J. Chem. Soc. Dalton Trans. pp. 1387-1393]. The distortion is caused by the difference in size between the O and S atoms. The benzene solvent mol-ecule is situated on a twofold rotation axis.
منابع مشابه
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عنوان ژورنال:
دوره 67 شماره
صفحات -
تاریخ انتشار 2011